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Chemistry – Atoms – Ions – Bonds

Atomic structure and isotopes

The number of protons determines the element, and the number of neutrons determines the isotope. It is necessary to distinguish between the mass number and the actual atomic mass.

Related experiment: Atoms and isotopes →
Atoms and isotopes
Atoms and isotopes: simulation view →

Meaning and mechanism

The atomic nucleus contains protons and neutrons, and electrons exist around it. Since the atomic number Z corresponds to the number of protons, losing electrons will not change the type of element.

Atoms of the same element with different numbers of neutrons are called isotopes. Carbon-12 and Carbon-14 have the same number of protons (6), but their neutrons are respectively 6 and 8.

Relationships and conditions

Mass number A represents the sum of the number of protons and the number of neutrons. It is obtained by subtracting the number of electrons from the number of protons.

Atomic mass number is an integer representing the number of nucleons. It is not equal to the actual atomic mass, which reflects the binding energy and the existence of isotopes, or the average atomic mass found in the periodic table.

What to observe in the simulation

Neutrons change isotopes, and electrons change ion charges. Elements are determined by the number of protons.

It's a particle counting model. The electron shell is an introductory schematic diagram and is not the actual circular orbit of an electron. Nucleus size and particle size are not proportional. Nuclear stability, decay, and electron configuration energies are not calculated.

Key relationships and symbols

Z = p · A = p + n · Charge = p − e

Symbols and units used in the formulas
SymbolMeaningUnit
ZProton number; atomic numberDimensionless
ANumber of protons + number of neutronsDimensionless
p, n, eNumbers of protons, neutrons, and electrons items

Worked example

Why are C-12 and C-14 the same element?

Elements are determined by the number of protons. Isotopes have the same number of protons but different numbers of neutrons.

Common misconceptions

  • The fact that the number of neutrons has changed does not mean that the element has changed. The criterion for distinguishing an element is the number of protons.

Explore this concept through experiments

References

OpenStax · Chemistry 2e (English)